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Week
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Topics
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Study Metarials
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1
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Definition and importance of organic chemistry, chemical bonds, okted rule, writing Lewis structures, formal charge, chemical formulas, functional groups.
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R1 Chapter 1 ve 2
R2 Chapter 1 ve 2
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2
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Atomic and molecular orbitals, hybrid orbitals of carbon (SP, SP2,SP3 hybridization), molecular geometry (VSEPR model), acids and bases (Lowry-Bronsted / Lewis acid-base concepts ), intermolecular interactions (dipole-dipole, hydrogen bonding).
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R1 Chapter 1 ve 3
R2 Chapter 1 ve 2
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3
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Basic reaction types in organic chemistry;
Substitution, addition, elimination, arrangements
reactions, reduction-oxidation reactions.
homolysis and heterolysis of covalent bonds, carbocathions and carbanions, the use of curved arrows in the representation of reactions. The concept of resonance.
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R1 Chapter 3, 6,7,8,11, 12, 16
R2 Chapter 2, 5,10, 13
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4
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Alkanes and cycloalkanes;
Nomenclature of alkanes, cycloalkanes and bicyclic alkanes, structure formulas, physical properties, usage areas. Synthesis and reactions of alkanes
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R1 Chapter 4
R2 Chapter 3
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5
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Alkenes ;
Nomenclature of alkenes, physical properties, stability and synthesis
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R1 Chapter 7
R2 Chapter 10
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6
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Addition reaction of alkenes:
Addition of water and sulfuric acid to alkenes, addition of water using mercury (II)acetate, addition of borane, halogen, HX, hydrogen, carbene to alkenes. Epoxidation of alkenes, oxidation of alkenes (syn hydroxylation)
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R1 Chapter 8
R2 Chapter 10
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7
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Alkynes;
The nomenclature, synthesis, acidity of alkynes.
Reactions of alkynes; hydrogen, halogen, HX, water addition. Oxidation of alkynes.
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R1 Chapter 7 ve 8
R2 Chapter 10
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8
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Stereochemistry: isomer types (constitutional and stereoisomers), conformation isomer of alkanes and cycloalkanes, the relative stabilities of cycloalkanes, Cis-Trans isomerism of cycloalkanes, geometric isomerism of alkene and cyclic compounds, E/Z system.
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R1 Chapter 4
R2 Chapter 4
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9
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Stereochemistry: isomer types (constitutional and stereoisomers), conformation isomer of alkanes and cycloalkanes, the relative stabilities of cycloalkanes, Cis-Trans isomerism of cycloalkanes, geometric isomerism of alkene and cyclic compounds, E/Z system.
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R1 Chapter 4
R2 Chapter 4
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10
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Stereochemistry: continued
The biological significance of chirality, determination of chirality, nomenclature of enantiomer : The R/S system, properties of enantiomers: optical activity and racemic mixtures, D,L system, chiral drugs.
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R1 Chapter 5
R2 Chapter 4
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11
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Stereochemistry: continued
Molecules with more than one stereogenic center, enantiomers, Diasteromers and Meso compounds, Fischer projection formulas, stereoisomerism of cyclic compounds, resolution of racemic mixtures, other asymmetric chiral molecules.
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R1 Chapter 5
R2 Chapter 4
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12
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Alkyl Halides;
Structure and importance, physical properties, classification and nomenclature of alkyl halides, nucleophilic substitution reactions (SN1, SN2), arrangements reactions in SN1 reactions.
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R1 Chapter 6
R2 Chapter 5
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13
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Alkyl Halides-continued
Elimination (E1, E2) reaction of alkyl halides.
Factors affecting substitution and elimination Reactions, Synthesis of other compounds from alkyl halides. Preparation of alkyl halides.
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R1 Chapter 6
R2 Chapter 5
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14
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Alcohols;
Structure , nomenclature, classification, basicity and acidity of alcohols, synthesis and reactions of alcohols
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R1 Chapter 11
R2 Chapter 7
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